If this is your first visit, be sure to
check out the FAQ by clicking the
link above. You may have to register
before you can post: click the register link above to proceed. To start viewing messages,
select the forum that you want to visit from the selection below.
+ anything that has sharpened edge or is (was?) hardened would be suspect to hydrogen embrittlement in electrolytic cleaning. Same problem with acids.
This is repeated over and over and over and over. It has been repeated so often "that everyone knows it". And I certainly am not denying it.
Has anyone actually done any testing to see to what degree this occurs? Is there any reference for it?
It makes sense, as there can be electrolysis of the water, and that end at the object to be de-rusted will be where the hydrogen goes to accept electrons. With a larger concentration of hydrogen around the object, diffusion into the metal is possible.
The question is whether it becomes a significant issue in the time needed for de-rusting. There must be some depth to which the diffusion reaches in a given time.
And, if so, why would a post-treatment baking not drive out the hydrogen?
Ideas expressed may be mine, or from anyone else in the universe.
Not responsible for clerical errors. Or those made by lay people either.
Number formats and units may be chosen at random depending on what day it is.
I reserve the right to use a number system with any integer base without prior notice.
Generalizations are understood to be "often" true, but not true in every case.
+ anything that has sharpened edge or is (was?) hardened would be suspect to hydrogen embrittlement in electrolytic cleaning. Same problem with acids.
Any lathe or mill cutters are not getting the bath. When needed I am scotchbriting the shanks clean, then trying them out .
If they are trash, into the Chinese recycle bin they go.
This is repeated over and over and over and over. It has been repeated so often "that everyone knows it". And I certainly am not denying it.
Has anyone actually done any testing to see to what degree this occurs? Is there any reference for it?
It makes sense, as there can be electrolysis of the water, and that end at the object to be de-rusted will be where the hydrogen goes to accept electrons. With a larger concentration of hydrogen around the object, diffusion into the metal is possible.
The question is whether it becomes a significant issue in the time needed for de-rusting. There must be some depth to which the diffusion reaches in a given time.
And, if so, why would a post-treatment baking not drive out the hydrogen?
Plenty of references if you check google for it. I have only personal experience from one plane iron that seemed to lose ability to hold edge after derusting. But truth to be told I can't remember how good it was even orginally 15 years ago.
MISUMI's Technial Tutorial site empowers engineers and designers in the
Factory Automation, Press and Mold industries to improve the efficiency of their design through valuable, in-depth tutorials.
Plenty of references if you check google for it. I have only personal experience from one plane iron that seemed to lose ability to hold edge after derusting. But truth to be told I can't remember how good it was even orginally 15 years ago.
MISUMI's Technial Tutorial site empowers engineers and designers in the
Factory Automation, Press and Mold industries to improve the efficiency of their design through valuable, in-depth tutorials.
Bake should work if you choose to do it.
They give a "rate", but it is not clear what the "rate" means in actual change in material properties. After all, that is the real issue. I did google it......
As for baking.... Dunno about that "" you sort of HAVE to do the baking, or not clean/put up with rust, or have fragile steel.
The common zinc-electroplated "drywall screw" is an example of what happens with a rough plating process and absolutely no care taken to deal with embrittlement. At last I assume so, since the standard ones do not break, but plated ones from the same manufacturer have broken off as much 3 times out of 5 when driving them (they are somewhat better now).
A blade that does not hold an edge.... in what way? does it dull? Or does the edge break off and chip? If it chips off, that is evidence for embrittlement, but if it just dulls, there is more chance that it is just softer steel.
Ideas expressed may be mine, or from anyone else in the universe.
Not responsible for clerical errors. Or those made by lay people either.
Number formats and units may be chosen at random depending on what day it is.
I reserve the right to use a number system with any integer base without prior notice.
Generalizations are understood to be "often" true, but not true in every case.
A blade that does not hold an edge.... in shat way? does it dull? Or does the edge break off and chip? If it chips off, that is evidence for embrittlement, but if it just dulls, there is more chance that it is just softer steel.
Throw it in he oven and see if that helps. If so, then you have GOOD evidence.
CNC machines only go through the motions.
Ideas expressed may be mine, or from anyone else in the universe.
Not responsible for clerical errors. Or those made by lay people either.
Number formats and units may be chosen at random depending on what day it is.
I reserve the right to use a number system with any integer base without prior notice.
Generalizations are understood to be "often" true, but not true in every case.
The problem with using electrolysis on the mystery metals you described is some of them will probably contain cadmium, chromium, nickel, and other metals. Those will end up in the solution, and I think they call that Hexavalent Chromium. That's very bad stuff, and it is verrry difficult to dispose of properly.
Comment